首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   5412篇
  免费   283篇
  国内免费   460篇
化学   2598篇
晶体学   242篇
力学   91篇
综合类   63篇
数学   2116篇
物理学   1045篇
  2023年   57篇
  2022年   68篇
  2021年   109篇
  2020年   101篇
  2019年   121篇
  2018年   97篇
  2017年   115篇
  2016年   127篇
  2015年   127篇
  2014年   162篇
  2013年   376篇
  2012年   207篇
  2011年   397篇
  2010年   380篇
  2009年   406篇
  2008年   396篇
  2007年   394篇
  2006年   314篇
  2005年   271篇
  2004年   259篇
  2003年   215篇
  2002年   198篇
  2001年   115篇
  2000年   121篇
  1999年   121篇
  1998年   93篇
  1997年   70篇
  1996年   92篇
  1995年   75篇
  1994年   61篇
  1993年   42篇
  1992年   42篇
  1991年   30篇
  1990年   15篇
  1989年   7篇
  1988年   10篇
  1987年   8篇
  1985年   38篇
  1984年   21篇
  1983年   20篇
  1982年   23篇
  1981年   44篇
  1980年   29篇
  1979年   13篇
  1978年   24篇
  1977年   30篇
  1976年   26篇
  1975年   20篇
  1974年   24篇
  1973年   20篇
排序方式: 共有6155条查询结果,搜索用时 46 毫秒
61.
We examine the propagation of shocks and traveling wave phenomena on a one-dimensional string that is executing finite-amplitude, transverse vibrations in a resisting medium. As part of our study, we develop an approach that allows us to describe, albeit approximately, the evolution and propagation of a shock front using analytical methods. In addition, exact traveling wave solutions, one of which involves the Lambert W-function, of the string's equation of motion are determined and analyzed. Lastly, a possible new form of the solution to the linearized problem is presented and extensions and other applications of the present work are briefly discussed.  相似文献   
62.
水工混凝土S-N和P-S-N曲线特性研究   总被引:5,自引:0,他引:5  
在已知混凝土静压强度分布的基础上使用S-N曲线模型推导出一种疲劳寿命满足的分布,并对水工混凝土做了大量的等幅抗压疲劳试验。通过分析发现,实验数据能较好地符合该分布,同时得出了该种混凝土的S-N曲线和P-S-N曲线。  相似文献   
63.
In this paper we develop a simple micromechanical model of a prestressed polycrystalline aggregate, in which the texture-induced and stress-induced anisotropies of the aggregate are precisely defined; here the word texture always refers to the texture of the aggregate at the given prestressed configuration, not to that of a perhaps fictitious natural state of the aggregate. We use this model to derive, for a prestressed orthotropic aggregate of cubic crystallites, a birefringence formula which shows explicitly the effects of the orthotropic texture on the acoustoelastic coefficients. From this formula we observe that, generally speaking, we cannot separate the total birefringence into two distinct parts, one reflecting purely the influence of stress on the birefringence, and the other encompassing all the effects of texture. The same formula, on the other hand, provides for each material specific quantitative criteria under which the separation of stress-induced and texture-induced birefringence would become meaningful in an approximate sense.  相似文献   
64.
力学可以为农业现代化作贡献   总被引:10,自引:0,他引:10  
华云龙  董务民 《力学进展》1998,28(3):289-298
农业现代化提出了许多与力学各个分支都有密切关系的问题.从农田耕作、农业物料性质、农产品烘干、水果和蔬菜生产、农业生物环境、节水灌溉、农业水土资源合理利用和作物生长等方面,介绍了有关的力学问题和目前的研究进展.  相似文献   
65.
In this work, we develop a low‐temperature, facile solution reaction route for the fabrication of quantum‐dot‐sensitized solar cells (QDSSCs) containing Ag2S‐ZnO nanowires (NWs), simultaneously ensuring low manufacturing costs and environmental safety. For comparison, a CdS‐ZnO NW photoanode was also prepared using the layer‐by‐layer growth method. Ultraviolet photoelectron spectroscopy analysis revealed type‐II band alignments for the band structures of both photoanodes which facilitate electron transfer/collection. Compared to CdS‐ZnO QDSSCs, Ag2S‐ZnO QDSSCs exhibit a considerably higher short‐circuit current density (Jsc) and a strongly enhanced light‐harvesting efficiency, but lower open‐circuit voltages (Voc), resulting in almost the same power‐conversion efficiency of 1.2 %. Through this work, we demonstrate Ag2S as an efficient quantum‐dot‐sensitizing material that has the potential to replace Cd‐based sensitizers for eco‐friendly applications.  相似文献   
66.
Two new abietane‐type diterpenoids, named triptobenzene R ( 1 ) and triptobenzene S ( 2 ), together with three known abietane‐type diterpenoids, triptophenolide ( 3 ), triptonodiol ( 4 ), and triptonoterpene methyl ether ( 5 ), were isolated from the roots of Tripterygium wilfordii Hook . f. Their structures and relative configurations were established by detailed spectral studies, including 1D‐ and 2D‐NMR (HSQC, HMBC, and NOESY), and HR‐ESI‐TOF‐MS, and by comparison with published data. Their absolute configurations were assigned by the CD technique, applied for the first time to abietane diterpenes from Tripterygium wilfordii. Compound 2 is the first abietane‐type norditerpenoid isolated from the genus Tripterygium.  相似文献   
67.
We present an existence result for Lévy‐type processes which requires only weak regularity assumptions on the symbol with respect to the space variable x. Applications range from existence and uniqueness results for Lévy‐driven SDEs with Hölder continuous coefficients to existence results for stable‐like processes and Lévy‐type processes with symbols of variable order. Moreover, we obtain heat kernel estimates for a class of Lévy and Lévy‐type processes. The paper includes an extensive list of Lévy(‐type) processes satisfying the assumptions of our results.  相似文献   
68.
Several chemical and biological studies have revealed R,S‐goitrin as the main bioactive constituent of Isatis indigotica Fort., responsible for antiviral antiendotoxin activity; however, few pharmacokinetic studies have been conducted. To comprehend the kinetics of R,S‐goitrin and promote its curative application, a rapid and sensitive UHPLC–MS/MS method was developed. The selected reaction monitoring transitions were m/z 130.0 → 70.0 for R,S‐goitrin and m/z 181.1 → 124.0 for the internal standard in a positive‐ion mode. The established UHPLC–MS/MS method achieved good linearity for R,S‐goitrin at 10–2000 ng/mL. The intra‐ and interday accuracy levels were within ±9.7%, whereas the intraday and interday precision levels were <11.3%. The extraction recovery, stability and matrix effect were within acceptable limits. The validated method was successfully applied for the pharmacokinetic analysis of R,S‐goitrin in rats after oral administration. Moreover, a total of six metabolites were structurally identified through UHPLC–Q/TOF–MS. The proposed metabolic pathways of R,S‐goitrin in rats involve demethylation, acetylation, glutathionylation and oxygenation.  相似文献   
69.
A new method for the determination of the 34S/32S ratio of water-extractable sulphate in soil is described. Soils are extracted directly with deionized water, which is evaporated down. The remaining residue is then rehydrated and transferred to tin cups containing an adsorbent and mixed with an oxygen donor (V2O5). Samples are then analysed using a continuous flow isotope ratio mass spectrometer. The new method requires around 10?g soil per determination, compared to much larger amounts (up to kilograms) of soil required for the previous methods. Sample preparation and subsequent analysis is quick and efficient. The method is demonstrated using a number of soils collected from around the world to provide a range of determined δ34S values. The δ34S values of water-extractable sulphur were broadly similar to those of the soil total sulphur.  相似文献   
70.
The endpoint Strichartz estimates for the Schrödinger equation is known to be false in two dimensions[7]. However, if one averages the solution in L2 in the angular variable, we show that the homogeneous endpoint and the retarded half­endoint estimates hold, but the full retarded endpoint fails. In particular, the original verisions of these estimates hold for radial data  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号